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In this thesis, a critical investigation is presented about the role of mechanical strain for the electron-transfer properties of the blue copper proteins. It has been found that the structure of a realistic model complex of the oxidised blue-copper active site, optimised in vacuum with the B3LYP method, has the same trigonal cupric geometry as in the protein. Thus, the protein does not strain the

We describe a system for automatic annotation of English text in the FrameNet standard. In addition to the conventional annotation of frame elements and their semantic roles, we annotate additional semantic information such as support verbs and prepositions, aspectual markers, copular verbs, null arguments, and slot fillers. As far as we are aware, this is the first system that finds this informat

The purpose of this article has been to examine the Swedish vocational education and training model with a special focus on basic education, within and outside the upper secondary school system. What can be said about the institutional structure of the educational system and how are new demands from working life concerning qualifications and mobility channelled through the system? The Swedish VET

Popular Abstract in Swedish Avhandlingens syfte är att genom en empirisk undersökning öka förståelsen av tidigt föräldraskap till barn med Downs syndrom. Jag utgår ifrån föräldrarnas livsvärld och utvecklar ett medföljande arbetssätt. Tio familjer med nyfödda barn med Downs syndrom följs genom regelbundna hembesök under det första året med barnet. Tillsammans med en medarbetare samtalar jag med föThe purpose of this dissertation was to increase - through an empirical investigation - our understanding of early parenthood in relation to children with Down syndrome. My point of departure has been the parents’ life-worlds, and I have developed an accompanying working method. Ten families with newborn infants with Down syndrome were followed through regular home visits during the first year of

Most energy behaviour studies on households focus on the questions how and why we use energy and what can be done to lower energy consumption. Very few studies raise the question of when energy is used or examine the underlying explanations to load patterns. Due to economic and technical problems with electricity peak load, it is important to gain knowledge about how the load patterns of household

Summary form only given. When designing symmetric ciphers, security and performance are of utmost importance. When selecting a symmetric encryption algorithm, the first choice is whether to choose a block cipher or a stream cipher. Most modern block ciphers offer a sufficient security and a reasonably good performance. But a block cipher must usually be used in a "stream cipher" mode of operation,

The kinetics and mechanism for substitution reactions on tetraaquapalladium(II) by an extended series of thioethers, a great number of carboxylic acids, and olefins have been studied by use of UV-VIS, stopped-flow, and high-pressure stopped-flow spectrophotometry and NMR spectroscopy. Second-order rate constants k and activation parameters (activation enthalpies, entropies, and volumes) for format

The unique properties of elastomeric materials are taken advantage of in many engineering applications. Elastomeric units are used as couplings or mountings between stiff structures. Examples of these are shock absorbers, vibration insulators, flexible joints, seals and suspensions.The development of computers and of analysis programs in this area has given engineers a new tool for the design of e

When designing symmetric ciphers, security and performance are of utmost importance. When selecting a symmetric encryption algorithm, the first choice is whether to choose a block cipher or a stream cipher. Most modern block ciphers offer a sufficient security and a reasonably good performance. But a block cipher must usually be used in a stream cipher mode of operation, which suggests that using

Increased mortality risks associated with smoking are well established among men. There are very few population-based studies comprising a sufficient number of heavily smoking women, measuring the direct effect of smoking on mortality risks. Between 1974 and 1992, 8,499 women and 13,888 men attended a health screening programme including reporting of smoking habits. Individuals were followed for t

The Late Ludlow topmost Hemse-Burgsvik succession includes more substantial and more rapid facies changes than most older and younger intervals on Gotland. A revised conodont zonation for this interval includes three zones, the Polygnathoides siluricus, the Icriodontid, and the Ozarkodina snajdri zones and four subzones, the Upper P. siluricus, the Lower, the Middle and the Upper Icriodonfid subzo

Objective: To report the outcome after ruptured abdominal aortic aneurysm (rAAA) repair in octo- and nonagenarians from the Swedish Vascular Registry 1994-2014. Material and methods: 2335 intact AAA (iAAA) and 1538 rAAA were identified in patients aged 80 years and older. Crude, long-term, and relative survival data were analysed using the Kaplan-Meier method. Crude survival was calculated includi

Studies of the structural dynamics of solids can improve our understanding of atomic motion in materials, and may thus help in the manufacture of new devices or the development of materials with novel structures and properties. Ultrashort laser pulses, a few tens of femtoseconds long, can deliver high energies (mJ–kJ). This energy is absorbed by the electrons in a solid material, leading to a rapi

Medical research generates a large number of publications with the PubMed database already containing >35 million research articles. Integration of the knowledge scattered across this large body of literature could provide key insights into physiological mechanisms and disease processes leading to novel medical interventions. However, it is a great challenge for researchers to utilize this informa

Background: Treatment guidelines recommend behaviour therapy (BT) for patients with Tourette syndrome (TS) and chronic tic disorder (CTD). However, BT is rarely accessible due to limited availability of trained therapists and long travel distances to specialist clinics. Internet-delivered BT has the potential of overcoming these barriers through remote delivery of treatment with minimal therapist

Smart vision sensor systems enable many computer vision applications such as autonomous drones and wearable devices. These battery-powered gadgets have very stringent power consumption requirements. Close-to-sensor feature extraction compressing the full image into descriptive keypoints, is crucial as it allows for several design optimizations. First, the amount of necessary on-chip memory can be

The research of psychiatry counselors’ work with compulsory care patients is very limited, if not non-existent. The aim of this study was therefore precisely that: to explore psychiatry counselors’ view on their work with compulsory care patients. The main method chosen was a qualitative questionnaire with nine psychiatry counselors from predominantly the regions of Skåne, Stockholm and Västra Göt

Denna uppsats studerar skiljeförfarandemekanismen i Convention of the Settlement of Investment Disputes Between States and Nationals of Other States (ICSID-konventionen) och hur den används i bilaterala investeringsavtal (BITs). Ämnet analyseras utifrån Third World Approach to International Law (TWAIL), vars synsätt utgår från att det finns en strukturell orättvisa i folkrätten och en dominans av