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Chloride anation of trans-Pt(CN)4ClOH2− has been studied with and without Pt(CN)42− present at 25.0°C by use of stopped-flow and conventional spectrophotometry and a 1.00 M perchlorate medium. The rate law in the absence of Pt(CN)42− is compatible with a chloride assistance via an intermediate of the type Cl-Cl-Pt(CN)4···OH22−, in which the reactivity of the aqua ligand is enhanced due to a partia

Popular Abstract in English Popular science Microbial cells are small and difficult to handle in industrial processes, especially if they are to be reused subsequent batches. In order to make them easier to handle, these cells can be attached to a solid support, by so-called immobilization. This provides particles of sizes that are easy to filter and reuse. However, immobilization is associated wiAbstract Due to the finite nature of fossil resources and their environmental impact, such as greenhouse gases and climate change, the bio-based production of chemicals, materials and fuels is the subject of extensive research in industrial biotechnology. Biotransformation and fermentation are considered to be mild, “green” processes that make use of effective and reliable biocatalysts to provide

The experimental results presented confirm the anticipation that it is extremely important not to confuse the concept of 'static loading' with the one of 'monotonic loading'. In principle three different crack configurations were investigated in: edge-cracks, internal flaws and surface cracks. The results showed that the same calculation method could be used for all the investigated crack types. T

https://www.msf.lu.se/5th-oresund-workshop-radiotherapy-february-8-9-2017 - 2026-05-07

Metastasis is a complex process that remains a major challenge in the clinical management of cancer, because most cancer-related deaths are attributed to disseminated disease rather than the primary tumor. Despite the significant advances in the prediction of prognosis, and therapeutic management of primary breast cancers, coupled with the substantial improvement in our understanding of the molecu

Popular Abstract in Swedish Jätteplaneterna, Jupiter, Saturnus, Uranus och Neptunus, är de största planeterna i solsystemet. De ligger långt från solen och har alla betydande gasatmosfärer, upp emot hundra gånger mer massiva än hela jorden. Tack vare de tjocka gashöljena, med en sammansättning som liknar solens, kan man förstå att jätteplaneterna bildades i en gasskiva. Denna skiva kallas för solGiant planets form embedded in a protoplanetary disc around a young star. Close to the midplane a large fraction of the available mass in solids is found in particles of cm to dm in size, which drift towards the star due to friction with the surrounding gas. In paper I, II, III we describe a novel theory that explains how embryos, planetesimals larger than ~1000 km, grow efficiently by sweeping up

Protein misfolding is a frequently occurring event in living cells and without the quality control, the consequences are disasterous. In this thesis, we studied protein misfolding in vitro by employing a variety of fluorophores, to either detect the highly ordered aggregates of intrinsically disordered proteins/peptides or slight misfolding of a natively folded protein. Misfolding and concurrent