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The structural properties in the ground and the excited states of the hexa-coordinated iron carbene molecule FeIII(phtmeimb)2PF6 were investigated by ultrafast time-resolved X-ray absorption spectroscopy (XAS)techniques. Namely X-ray absorption near edge structure (XANES) and Extended X-ray Absorption FineStructure (EXAFS). Data from a time-resolved pump-probe synchrotron radiation experiment was
