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Oxygenases are a group of enzymes that use molecular oxygen to oxidize a substrate, a very important process both biologically and industrially. High-valent Fe(IV)-oxo species have long been implicated as the key reactive intermediates in heme and non-heme iron oxygenases. Since the first well-characterized mononuclear non-heme iron(IV)-oxo complex was reported in 2003, much effort have been put i
