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SynopsisReactivity trends of thioethers toward square-planar complexes can be generally interpreted by use of an equation of the form: log k = γ + α∑σ* + βθ, where k denotes second-order rate constants, ∑σ* the sum of Taft constants for the thioether substituents, and θ the thioether cone angles. γ represents an intrinsic parameter for each substrate complex, while α is an electronic and β a sterSynopsisReactivity trends of thioethers toward square-planar complexes can be generally interpreted by use of an equation of the form: log k = γ + α∑σ* + βθ, where k denotes second-order rate constants, ∑σ* the sum of Taft constants for the thioether substituents, and θ the thioether cone angles. γ represents an intrinsic parameter for each substrate complex, while α is an electronic and β a ster