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Hexameric arginine repressor, ArgR, bound to L-arginine serves both as the master transcriptional repressor/activator at diverse regulons in a wide range of bacteria and as a required cofactor for resolution of ColE1 plasmid multimers. Multifunctional ArgR is thus unusual in possessing features of specific gene regulators, global regulators, and non-specific gene organizers; its closest functional

This article discusses A-licensing and case from a minimalist perspective, pursuing the idea that argument NPs cyclically enter a number of A-relations, rather than just a single one, resulting in event-licensing, case-licensing and phi-licensing. While argument case commonly reflects Voice/v-relations, canonical A-movement is driven by higher elements, either in the C-T system or in a superordina

Scanning tunneling microscopy (STM) studies of monolayer of metal-free phthalocyanine (H2Pc) adsorbed on Au(111) have shown ordered arrangement of the molecules on the surface. Evaporation of H2Pc onto the Au(111) surface and post annealing of the sample to 670 K results in a densely packed structure of the molecules. The monolayer is characterized by molecules adsorbed with the molecular plane pa

Pb2+ complexes can attain several different topologies, depending of the shape of the Pb 6s6p lone pair. In this paper, we study structures with a bisdirected Pb lone pair with quantum mechanics (DFT) and QM/MM calculations. We study small symmetric Pb2+ models to see what factors are needed to get a bisdirected lone pair. Two important mechanisms have been found: First, the repulsion of the lone

To obtain knowledge about combustion mechanisms operating in the ammoxidation of toluene, the formation of carbon oxides was studied over a Ti02(B)-supported vanadium oxide catalyst with monolayer loading. The partial pressures of reactants were varied and kinetic rate expressions, completely describing experimental data, were derived. A comparison of the expressions obtained with those for the fo

Selective catalytic reduction of NOx (SCR) has been recognised as an effective post-combustion method for reducing nitrogen oxides from stationary sources. The cost of replacing the catalyst is a major part of the maintenance of the SCR system, hence it is desirable to advance methods to prolong the catalyst life. The objectives of this thesis were to investigate the extent and the mechanism of de

Requirements on well documented management systems for Nuclear Power Plants (NPPs) are relatively new and in different developmental phases. Thus there is a need of knowledge about well-functioning Safety Management Systems (SMSs) also considering other goals and restrictions. Since there ia a lack of mature management systems for NPPs it is important to learn from other NPPs, but also from other

The enlargement of the European Union provides opportunities for members to be mobile in seeking various forms of permanent and non-permanent employment, particularly temporary work and contract labour. These changing conditions require quick reactions, overcoming soft issues such as language barriers and coping with culture clashes and political issues that could create problems for the worker. W

The early medieval cult of saints has been the object of many illuminating studies during the past decades. However, one aspect in need of more research is the role of the cults in the building of early states in Europe, a phenomenon that is often, somewhat erroneously, referred to as the cult of national saints. The saints were powerful assets in the attempts of kings, dukes and bishops at achiev

This thesis concerns the analysis of anthropogenic substances of the compound class known as persistent organic pollutants (POPs). Sample preparation perspectives for the analysis of POPs in the environmental matrices water, soils and sediments are presented. This thesis features reasonably cheap and uncomplicated methodology capable of fast screening of POPs. It displays how quantitative extract

Popular Abstract in English The chemical industry has greatly contributed to the advancement of the human civilization. However, the side effects of this industry have become a real environmental burden. The message in this thesis is that enzymes have a great potential as catalysts for clean and sustainable processes. With three enzymes: an esterase, a lipase and a phytase, the thesis demonstratedThe use of enzymes in industrial applications has been recognised for providing clean processes with minimal impact on the environment. This thesis presents studies on engineering of enzymes and enzyme-based processes in the light of green chemistry and environmental sustainability, and focuses on three hydrolases: esterase, lipase and phytase. The use of esterase has been investigated to provide

Large areas of peatlands have worldwide been drained to facilitate agriculture, which has adverse effects on the environment and the global climate. Agriculture on rewetted peatlands (paludiculture) provides a sustainable alternative to drainage-based agriculture. One form of paludiculture is the cultivation of Sphagnum moss, which can be used as a raw material for horticultural growing media. Und

2'-Deoxy-N(6)-methyladenosine (N(6)mdA) is frequently found in prokaryotic and unicellular eukaryotic genomes. Although methylated bases represent only a minor fraction of the genome, they, however, exhibit strong biological effects. Here, we report a fast and sensitive method for the quantification of global adenine methylation in DNA. The method is based on a recently developed procedure consist

Each year, approximately one in 1000 individuals suffers from venous thromboembolism. The pathogenesis of the disease is multifactorial and a thrombotic event is the result of a combination of genetic and circumstantial risk factors. Until recently, genetic defects could only be identified in a minority of thrombosis patients. The discovery of inherited resistance to activated protein C as a risk