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Kinetics and Mechanism for Reduction of trans-Dichlorotetracyanoplatinate(IV) by Thioglycolic Acid, L-Cysteine, D,L-Penicillamine, and Glutathione in Aqueous Solution

SynopsisVarious protolytic species of thiols RSH (thioglycolic acid, l-cysteine, dl-penicillamine, and glutathione) in rapid equilibria with each other reduce trans-[Pt(CN)4Cl2]2- in parallel, halide-bridged electron transfer reactions. A linear Brønsted correlation between the reactivity of the thiolate anions RS- and their basicity is observed. The mechanism derived might be used as a model for

New materialism, depression and antidepressants: at the 9th European Feminist Research Conference, Sex & Capital, 3-6 June, 2015, University of Lapland, Rovaniemi, Finland : engaging in feminist dialogues about the body and biology

In this paper I will engage in a dialogue with new materialism within feminist theory. I will do this though depression and the use of the type of antidepressants named SSRIs (selective serotonin reuptake inhibitors), often talked about under the commercial brand of Prozac, and through the work of Elizabeth Wilson. I have researched experiences of using antidepressants through in-depth interviews,

Investigation of the Fuel Distribution and the In-Cylinder Flow Field in a Stratified Charge Engine Using Laser Techniques and Comparison with CFD-Modelling

This paper presents an investigation of a Volvo Direct Injection Spark Ignition (DISI) engine, where the fuel distribution and the in-cylinder flow field have been mapped by the use of laser techniques in an engine with optical access. Along with the experimental work, CFD-modelling of flow and fuel distribution has been performed.Laser Induced Fluorescence (LIF) visualisation of the fuel distribu

Governing Mobility-as-a-Service : Insights from Sweden and Finland: Towards New Organizational Structures for the Development of Shared, Automated, Electric and Integrated Mobility

Based on a review of recent developments in Sweden and Finland, this chapter analyzes the roles of public organizations in the governance of a transition to Mobility-as-a-Service (MaaS). In particular, we draw on insights from transition frameworks to explore what these two pioneering cases can teach us about how the public sector can both enable the development of MaaS and steer the development t