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Kinetics and Mechanism for Reduction of trans-Dichlorotetracyanoplatinate(IV) by Thioglycolic Acid, L-Cysteine, D,L-Penicillamine, and Glutathione in Aqueous Solution

SynopsisVarious protolytic species of thiols RSH (thioglycolic acid, l-cysteine, dl-penicillamine, and glutathione) in rapid equilibria with each other reduce trans-[Pt(CN)4Cl2]2- in parallel, halide-bridged electron transfer reactions. A linear Brønsted correlation between the reactivity of the thiolate anions RS- and their basicity is observed. The mechanism derived might be used as a model for

Axes of resonance in music education : An artographic exploration

This article discusses the potentials of a/r/tography aka artography against the background of life in an accelerating academia that is increasingly shallow and unfulfilling, and where quality is only indirectly measured using bibliometrics. We find Hartmut Rosa’s concept of resonance to be useful when discussing the values that get lost in such a system. We appreciate the arguments for a slower,